| 付斌,周蓉,姚玉平,张博,赵巧巧,王胜丹.纳米纤维素疏水疏油功能化改性及应用研究进展[J].中国造纸,2025,44(10):50-56 |
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| 纳米纤维素疏水疏油功能化改性及应用研究进展 |
| Research Advances in Hydrophobic-Oleophobic Functionalization of Nanocellulose and Its Applications |
| 收稿日期:2025-05-30 修订日期:2025-08-18 |
| DOI:10.11980/j.issn.0254-508X.2025.10.006 |
| 关键词: 纳米纤维素 疏水疏油功能化改性 生物基材料 |
| Key Words:nanocellulose hydrophobic-oleophobic functionalization bio-based materials |
| 基金项目:山东省高等学校青年创新团队项目(2023KJ330);全国重点实验室建设重大科研专项(2025ZDGZ02)。 |
| 作者 | 单位 | 邮编 | | 付斌* | 齐鲁工业大学(山东省科学院)绿色造纸与资源循环全国重点实验室,山东济南,250353 | 250353 | | 周蓉 | 齐鲁工业大学(山东省科学院)绿色造纸与资源循环全国重点实验室,山东济南,250353 | 250353 | | 姚玉平 | 青岛特锐德电气股份有限公司,山东青岛,370200 | 370200 | | 张博 | 齐鲁工业大学(山东省科学院)绿色造纸与资源循环全国重点实验室,山东济南,250353 | 250353 | | 赵巧巧 | 齐鲁工业大学(山东省科学院)绿色造纸与资源循环全国重点实验室,山东济南,250353 | 250353 | | 王胜丹* | 齐鲁工业大学(山东省科学院)绿色造纸与资源循环全国重点实验室,山东济南,250353 | 250353 |
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| 摘要:纳米纤维素作为一种新型生物基材料,具有可再生、可降解性、高比表面积、力学性能优异等特点,但其表面含有大量亲水性羟基,限制了其在疏水疏油领域的应用。因此,纳米纤维素的疏水疏油功能化改性逐渐成为科技工作者们的研究热点。本文系统综述了纳米纤维素疏水疏油功能化改性原理、方法及应用领域,归纳了不同改性方法对应的产品特性,重点评述了疏水疏油改性纳米纤维素在食品包装、纺织领域、造纸行业的应用进展,分析了纳米纤维素基疏水疏油材料规模化应用存在的技术瓶颈与挑战,展望了纳米纤维素基疏水疏水功能材料的未来研究方向,为开发高性能纳米纤维素基疏水疏油材料提供理论支持。 |
| Abstract:As a novel bio-based material, nanocellulose exhibits distinctive attributes including renewability, degradabiility, high specific surface area, and exceptional mechanical performance. However, its surface contains abundant hydrophilic hydroxyl groups, which limits its application in hydrophobic-olephoic fields. Consequently, the hydrophobic-oleophobic functionalization modification of nanocellulose has progressively emerged as a research focus among scientists. In this paper, the principles, methodologies, and applications of hydrophobic-oleophobic functionalization modification of nanocellulose were systematically reviewed, while the characteristic features of products derived from distinct modification approaches were categorized. Applications of hydrophobic-oleophobic modified nanocellulose in food packaging, textile industries, and paper manufacturing were critically evaluated. Technical bottlenecks hindering the scaled application of these materials were analyzed, and future development directions were prospected to provide theoretical foundations for designing high-performance nanocellulose-based hydrophobic-oleophobic systems. |
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