| 卢志锋,徐桂龙,唐敏,宋强,梁云.新型纸基除湿材料的制备及其性能研究[J].中国造纸,2026,45(5):32-38 |
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| 新型纸基除湿材料的制备及其性能研究 |
| Preparation and Properties of a Novel Paper-based Desiccant Material |
| 收稿日期:2025-11-13 修订日期:2025-12-04 |
| DOI:10.11980/j.issn.0254-508X.2026.05.004 |
| 关键词: 纸基除湿材料 聚丙烯酸钠树脂 吸湿率 循环稳定性 |
| Key Words:paper-based dehumidification material sodium polyacrylate resin moisture absorption rate cycling stability |
| 基金项目:中央高校基本科研业务费专项资金。 |
| 作者 | 单位 | 邮编 | | 卢志锋* | 1华南理工大学轻工科学与工程学院,广东广州,510640 | 510640 | | 徐桂龙* | 1华南理工大学轻工科学与工程学院,广东广州,510640 2华南理工大学造纸与污染控制国家工程研究中心,广东广州,510640 | 510640 | | 唐敏 | 1华南理工大学轻工科学与工程学院,广东广州,510640 2华南理工大学造纸与污染控制国家工程研究中心,广东广州,510640 | 510640 | | 宋强 | 1华南理工大学轻工科学与工程学院,广东广州,510640 2华南理工大学造纸与污染控制国家工程研究中心,广东广州,510640 | 510640 | | 梁云 | 1华南理工大学轻工科学与工程学院,广东广州,510640 2华南理工大学造纸与污染控制国家工程研究中心,广东广州,510640 | 510640 |
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| 摘要:本研究以竹浆、玻璃纤维和双熔点聚对苯二甲酸乙二醇酯(PET)纤维为原料,采用湿法成形工艺制备多孔纤维基材,并通过浸渍法负载聚丙烯酸钠(PAAS)树脂,开发出一种新型纸基除湿材料。系统研究了纤维配比、热压时间及PAAS树脂留着量对材料结构与性能的影响。结果表明,按照竹浆、双熔点PET纤维、短切玻纤质量比=4∶3∶3进行抄造,92 ℃热压8 min,PAAS树脂留着量为140%时,所得纸基除湿材料综合性能最佳,其抗张指数为29.5 N·m/g,挺度为1.22 mN·m,耐破度为149 kPa;在30 ℃、相对湿度90%环境下的平衡吸湿率为76%,吸湿后纸基除湿材料的抗张指数、挺度、耐破度分别保持在7.44 N·m/g、0.70 mN·m、149 kPa,并表现出良好的低温放湿特性。经过50次吸放湿循环后,材料吸湿容量基本保持不变,显示出良好循环稳定性。 |
| Abstract:This study presented a novel paper-based desiccant material fabricated through a wet-forming process. A porous fibrous substrate was first prepared from bamboo pulp, glass fibers, and dual-melting-point polyethylene terephthalate (PET) fibers, and then impregnated with sodium polyacrylate (PAAS) resin. The effects of fiber composition, hot-pressing time, and PAAS retention on the material’s structure and properties were systematically investigated. Results showed that the optimal performance was achieved with a mass ratio of 4∶3∶3 for the dual-melting-point PET fibers, bamboo pulp, and chopped glass fibers, respectively, after hot-pressing at 92 ℃ for 8 min and with a resin retention of 140%, exhibited optimal overall performance. Its tensile index was 29.5 N·m/g, stiffness 1.22 mN·m, and burst strength 149 kPa. Under conditions of 30 ℃ and 90% relative humidity (RH), the equilibrium moisture absorption rate reached 76%. After moisture absorption, the tensile index, stiffness, and burst strength were maintained at 7.44 N·m/g, 0.70 mN·m, and 149 kPa, respectively, along with demonstrating good low-temperature moisture release characteristics. Remarkably, its moisture absorption capacity remained virtually unchanged over 50 absorption-desorption cycles, indicating exceptional cycling stability. |
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