| 边永峰,杨扬,曾鹏霖,朝鲁门,钟林新.聚吡咯纸基柔性超级电容器电极的制备及其性能研究[J].中国造纸,2026,45(10):114-127 |
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| 聚吡咯纸基柔性超级电容器电极的制备及其性能研究 |
| Preparation and Performance Study of Polypyrrole Paper-based Flexible Supercapacitor Electrodes |
| 收稿日期：2026-05-11 修订日期：2026-06-10 |
| DOI：10.11980/j.issn.0254-508X.2026.10.013 |
| 关键词: 聚吡咯 纸基电极 超级电容器 植物纤维 |
| Key Words:polypyrrole paper-based electrode supercapacitor plant fiber |
| 基金项目: |
| 作者 | 单位 | 邮编 | | 边永峰* | 1华南理工大学轻工科学与工程学院,广东广州,510640 | 510640 | | 杨扬 | 2中国制浆造纸研究院有限公司,北京,100102 | 100102 | | 曾鹏霖 | 1华南理工大学轻工科学与工程学院,广东广州,510640 | 510640 | | 朝鲁门* | 2中国制浆造纸研究院有限公司,北京,100102 | 100102 | | 钟林新* | 1华南理工大学轻工科学与工程学院,广东广州,510640 | 510640 |
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| 摘要:本研究通过浸渍原位聚合的方法，以天然植物纤维与吡咯为原料，制备聚吡咯（PPy）纸基柔性电极，并探讨了不同制备工艺条件（吡咯浸渍液浓度、浸渍次数、打浆度和植物纤维原料品种）对PPy纸基柔性电极的影响。结果表明，在最佳工艺条件（吡咯浸渍液浓度30%（体积分数）、浸渍次数2次、打浆度35 °SR）下漂白硫酸盐阔叶木浆纤维制备的PPy纸基柔性电极的电导率达9.83 S/cm，在5 mA/cm2电流密度下，面积比电容达1 934.66 mF/cm2。将其组装成固态超级电容器，表现出优异的电化学性能与柔性稳定性：5 mA/cm²电流密度下面积比电容达393.50 mF/cm²，1 000次充放电循环后电容保持率高，180°弯折500次后容量仅衰减9.1%。 |
| Abstract:The study used natural plant fibers and pyrrole as raw materials, the polypyrrole-based paper flexible electrodes were fabricated via in-situ polymerization after impregnation. This study investigated the effects of various preparation parameters (pyrrole impregnation concentration, impregnation cycles, beating degree, and types of plant fibers) on polypyrrole-based paper flexible electrodes. The results showed that under the optimal preparation conditions (pyrrole impregnation concentration of 30% (volume fraction), impregnation times of 2, beating degree of 35 °SR), bleached kraft hardwood plup fiber prepared electrode achieved an electrical conductivity of 9.83 S/cm and an areal specific capacitance of 1 934.66 mF/cm² at a current density of 5 mA/cm². Solid-state supercapacitors were assembled using the obtained polypyrrole-based paper electrodes, which exhibited outstanding electrochemical performance and mechanical flexibility. The assembled device delivered an areal specific capacitance of 393.50 mF/cm² at 5 mA/cm², and maintained a high capacitance retention after 1 000 charge-discharge cycles. After 500 bending cycles at 180°, the capacitance only decayed by 9.1%. The devices met the application requirements of flexible energy storage systems and were promising for flexible supercapacitor applications. |
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